The official site for Charlotte has listed an unaired episode to be included in the seventh Blu-ray and DVD volume. The volume, which also includes episode thirteen, will be released on March 23.
Charlotte is an original project created by Key and P.A. Works. The anime premiered this Summer and is currently on-going, while the manga was serialized in Dengeki G's Comic in July.
Source: Official site
Charlotte Special on MAL
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Anime